科研方向为一碳化工和等离子体催化,绿色工艺开发,非均相催化与反应工程。
绿色化学工艺,化工安全与环保
教育部新世纪优秀人才,在二氧化碳捕集和转化、等离子体化学与催化、费-托合成工艺研发及二氧化碳甲烷化等方面开展研究工作,主持国家 863 计划项目、国家重点研发计划项目、国家自然科学基金重点项目和面上项目等10项,在Appl Catal B、Chem Eng J、ACS Appl Mater Interfaces、Chem Eng Sci、Fuel等期刊发表SCI论文150余篇,获授权美国、欧洲、日本发明专利6项和中国发明专利10项。作为主要参加人获得教育部技术发明一等奖、石化联合会技术发明一等奖、天津市专利金奖、中国专利优秀奖各1项。
主持项目如下:
(1)国家自然科学基金项目4项:“等离子体技术对催化剂表面改性作用的研究”和“等离子体制备高分散钴基费-托合成催化剂及其性能研究”、“钼基催化剂MoS2结构和尺寸调控及其对耐硫甲烷化性能的影响”、“新型核-腔-壳Co/SiO2@void@ZSM-5纳米反应器构建及其协同催化合成气一步高选择性合成汽油”。
(2)天津市自然科学基金项目2项:“天然气低温等离子体转化制碳二烃”和“耐硫甲烷化钼基催化剂中MoS2结构和尺寸调控研究”
(3)国家863项目1项:“钙基工业固废制备脱硫剂及脱硝固废再生技术与示范--以电石渣为原料制备脱硫剂甲酸钙成套技术开发”。
(4)国家重点研发计划项目1项,“用于 CO2 捕集的高活性低能耗固体吸附材料及技术”子课题“新型高活性低成本CO2固体吸附材料的规模化制备技术”
发表论文:
(1). Qiang Wang, Zhenhua Li, Xinbin Ma,Electronic regulation of MoS2 edge sites by d electron transfer of Ni or Co to improve the activity of CO sulfur-resistant methanation,Chemical Engineering Journal,480 (2024) 148242
(2). Qiang Wang, Longchen Gong, Zhenhua Li,Intrinsic kinetics of CO sulfur-resistant methanation over the curved MoS2 catalyst,Molecular Catalysis 568 (2024) 114513
(3). Shuangxi Lin, Zhenhua Li,Modulating CO2 methanation activity on Ni/CeO2 catalysts by tuning ceria facet-induced metal-support interaction,International Journal of Hydrogen Energy,51 (2024) 462
(4). Shuangxi Lin, Zhenhua Li, Wen Liu,Tailoring metal-support interactions via spatial confinement of Ni/CeO2 interfaces on h-BN for efficient CO2 methanation,Chemical Engineering Journal 494 (2024) 152937
(5). Tingting Wang, Rui Tang , Zhenhua Li,Enhanced CO2 methanation activity over Ni/CeO2 catalyst by adjusting metal-support interactions,Molecular Catalysis 558 (2024) 114034
(6). Qiang Wang, Yifei Wang, Zhenhua Li, Xinbin Ma,DFT study on doping effect of different transition metals on MoS2 for enhancing the formation of S vacancies,International Journal of Hydrogen Energy 82 (2024) 416
(7). Shuangxi Lin, Zhenhua Li, Maoshuai Li, Tailoring metal-support interactions via tuning CeO2 particle size for enhancing CO2 methanation activity over Ni/CeO2 catalysts, Fuel, 2023, 333(1): 126369
(8). Meng Su, Xin Li, Zhenhua Li, A hybrid plasma-catalysis system for CO2 hydrogenation over perovskite-type catalysts: Promoting effect of A-site substitution, Energy Technology, 2023, 11: 2200817
(9). Xudong Liu, Lijuan Zhang, and Zhenhua Li, Promotion Effect of TiO2 on Ni/SiO2 Catalysts Prepared by Hydrothermal Method for CO2 Methanation. Energy Technology, 2023, DOI: 10.1002/ente.202201526
(10). Ning Zhao, Yao Chen, Zhenhua Li, Modulating Co reduction degree and Fischer-Tropsch synthesis performance by reducing cobalt silicate at different conditions, Molecular Catalysis, 2023, 549: 113483
(11). Niamat Ullah, Zhenhua Li, Enhanced CO2 hydrogenation to light hydrocarbons on Ni-based catalyst by DBD plasma, International Journal of Hydrogen Energy, 2023, https://doi.org/ 10.1016/j.ijhydene.2023.03.006
(12). Tang Rui, Li Zhenhua. Unveiling the promotion effect of Zr species on SBA-15 supported nickel catalysts for CO2 methanation, International Journal of Hydrogen Energy, 2023, 48(12): 4694
(13). Wang, Qiang; Ma Xinbin, Li Zhenhua, Enhancing stability of MoS2 catalysts for sulfur-resistant methanation by tuning interlayer interaction,Molecular Catalysis, 2022, 517: 112057
(14). Wang, Qiang; Li Zhenhua, Activation of the MoS2 basal plane to enhance CO hydrogenation to methane activity through increasing S vacancies, ACS Appl. Mater. Interfaces, 2022, 14 (6): 7741
(15). Mehar U Nisa, Yao Chen, Zhenhua Li, Modulating C5+ selectivity for Fischer-Tropsch synthesis by tuning pyrolysis temperature of MOFs derived Fe-based catalyst, Journal of the Taiwan Institute of Chemical Engineers, 2022, 131: 104170
专利:
1.马新宾,黄守莹,王胜平,赵玉军,袁勇,李振花,王悦,α-三氧化二铝负载四氧化三铁的催化剂及其制备方法,CN201710277965.9,2021.3.9
2.吕静,李振花,刘芳,曹新原,马新宾,由黄磷尾气制备甲酸钙的连续生产方法,CN201710791173.3,2021.5.14
3.马新宾,黄守莹,袁勇,王洪宇,吕静,李振花,含有助剂的α-三氧化二铝负载双金属氧化物的催化剂及其制备方法,CN201710277371.8,2021.6.1
4.黄守莹,袁勇,马新宾,吕静,李振花,王胜平,赵玉军,含有助剂的α-三氧化二铝负载四氧化三铁的催化剂及其制备方法, CN201710277970.X,2021.6.1
研究生导师类型 |
专业型硕导,学术型硕导,学术型博导,专业型博导 |
学术型硕士招生学科 |
081702化学工艺 |
学术型硕士招生研究方向 |
00不区分研究方向 |
专业型硕士招生学科 |
085600材料与化工(专业学位) |
专业型硕士招生研究方向 |
02化学工艺 |
学术型博士招生学科 |
081702化学工艺 |
专业型博士招生学科 |
085600材料与化工 |